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The reaction converts saturated heterocycles with 6 atoms, including cyclic amines, ethers (example shown), and thioethers, into 5-carbon rings with pendant amines, alcohols, or thiols, respectively.
Chemists at the University of Oklahoma have now unveiled a new strategy for expanding 5-membered aromatic rings that already contain a nitrogen, by slipping in an extra nitrogen atom as the ring ...
Creation of negatively curved polyaromatics enabled by annulative coupling that forms an eight-membered ring. Nature Catalysis , 2020; DOI: 10.1038/s41929-020-0487-0 Cite This Page : ...