The binding of [5‘-3H]inosine to human purine nucleoside phosphorylase results in an equilibrium binding isotope effect (BIE) of 1.5%, and transition state formation causes an intrinsic KIE of 4.7%.

Global utilities generated a record amount of clean electricity while cutting output from fossil fuels during the opening ...

Speeding up chemical reactions is key to improving industrial processes or mitigating unwanted or harmful waste. Realizing ...

A series of 16 molecular rotors were synthesized to investigate the ability of n→π* interactions to stabilize transition states (TSs) of bond rotation. Steric contributions to the rotational barrier ...

In this study, a population-based continuous state transition algorithm (STA) is investigated into continuous constrained optimization problems. After an analysis of the advantages and disadvantages ...