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The reaction of colorless iron(II) formate or the mixed-valence cluster Fe3O(MeCOO)6(H2O)3 with formic acid in dimethylformamide exposed to air at 110 °C affords black crystals of the mixed-valence ...

The synthesis and crystallographic characterization of the five-coordinate iron(III) porphyrinate complex [Fe(OEP)(NO)]ClO4 are reported. This {FeNO}6 complex has a nearly linear Fe−N−O group (angle = ...